This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically. The degree of sensitization dos was quantified by the double loop electrochemical potentiokinetic reactivation. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Stress corrosion cracking of ring type joint of reactor pipeline of. Brittle fracture is the sudden, very rapid cracking of equipment under stress where the material exhibited little or no evidence of ductility or plastic degradation before the fracture occurs. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns.
What are the industrial practices being followed in. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. Stress corrosion cracking behavior of materials intechopen. Alloy 321 resists polythionic acid stress corrosion cracking in hydrocarbon service. In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance. Stabilized austenitic stainless steels sss have since been widely used in the petroleum refining industry because of their resistance to sulphidic corrosion and polythionic acid stress corrosion cracking scc, as well as of their excellent strength and toughness. Analysis of fracture surfaces using scanning electron microscopy. Trithionic acid h 2 s 3 o 6, tetrathionic acid h 2 s 4 o 6 are simple examples. In this chapter, the conditions for the occurrence of scc are first introduced. A slow strain rate tensile ssrt test was used to investigate the effect of laser shock peening lsp on stress corrosion cracking scc behavior of the 304 austenitic stainless steels asss in acid chloride solution. Polythionic acid stress corrosion cracking occurs on sensitized stainless heater tubes in hydroprocessing units. Alloy 321 stainless steel plate does not perform well in chloride solutions, even in small concentrations, or in sulfuric acid service. They can be subject to polythionic acid stress corrosion cracking during shut down.
Stress corrosion cracking issues in syngas plants that may. Cracking investigation of a pressure transmitter tapping line. The alloys comprising of 42 45% nickel will not be attacked in this. In the presence of sulfide corrosion products, such conditions are met during shutdown, when moisture originates from general humidity, washing or steam out and oxygen as air enters the unit upon opening to atmosphere. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Pta treat is a formula designed to prevent polythionic acid pta stress corrosion cracking on 300 series stainless steel and certain alloys.
Detailed metallurgical investigation was carried out to identify the probable causes that could. Naphthenic acid a collective name for organic acids found primarily in crude oils from western united states, certain texas and gulf coast and a few mideast oils. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. Two examples of stress corrosion cracking scc in refinery equipment are presented to highlight the lessons learned to prevent recurrence of such failures. Cracking of sensitized stainless steels inspectioneering. Polythionic acid stress corrosion cracking in heater pipes. Polythionic acid stress corrosion cracking deterioration. Why does chloride stress corrosion cracking and pascc only. The cracks are intergranular and narrow with no significant branching. In certain process units, such as hydrocracking, soda ash washing neutralization of austenitic stainless steel is required during turnarounds to mitigate the potential for polythionic acid stress corrosion cracking pta scc. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking.
Jsm 35 scanning electron microscope equipped with energy dispersive xray. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these. However, in some instances, stabilized austenitic sss have been found to be susceptible to pitting, crevice. The item was exposed to sulfur containing natural gas in a continuous flare.
Bradley and others published alloy for resistance to polythionic acid stress corrosion cracking for hydroprocessing. The sem and eds results indicate that the corrosion medium i. Based on this analysis the leaks were caused by cracks that initiated on the id surface. Nickelchromiummolybdenum alloys the main drawbacks of stainless steels is that these alloys are sensitive to chloride induced localized attack like pitting and crevice attack and stress corrosion cracking. Polythionic acid stress corrosion cracking, mechanical. Stress corrosion cracking occurred at the drain valve connection piping located upstream of an emergency shutoff valve at the outlet of a hydrogen heating furnace, resulting in a hydrogen leak and fire. An austenitic stainless steel for sulfuric acid corrosion environments. Corematerials polythionic stress corrosion cracking of. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Download citation effect of chloride ion on stress corrosion cracking of type 316. Stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution. The degree of sensitization dos was quantified by the double loop electrochemical potentiokinetic reactivation dlepr method.
The test may not be relevant to stresscorrosion cracking in polythionic acid or caustic environments. Chloride stress corrosion cracking of an austenitic. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid.
Stress corrosion cracking is induced by polythionic acid. Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen and water. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Type 304l shares disadvantages of 304h it does sensitize at high temperature, however and can be susceptible to polythionic acid stress corrosion cracking during shut down, especially if the regenerator is water washed. They have high strength, excellent fabrication characteristics, and can readily meet a wide range of design demands load, service life, low maintenance, etc.
For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Pascc polythionic acid stress corrosion cracking oil. Stress corrosion cracking scc investigations of sensitized 304 austenitic stainless steel were conducted using ubend specimens of 6. Concentrated water with other aggressive agents such as caustic and chlorides leaked through the cracks aid the failures. Polythionic acid neutralization and decontamination process. Stress corrosion cracking and component failure 169. Subsequently, this particular form of intergranular scc was called polythionic acid stress corrosion cracking pascc. Ctlpolythionic stress corrosion cracking of stainless steel tube. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a te nsile s tress, especially at elevated temperature. Stress corrosion cracking can proceed in one of two ways. The applications for stainless steels in petroleum refining are many and varied.
Two corrosion tests were conducted for these welded joints without and with stabilization at 900 deg. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. Sulfur can come from feed stock, additives or fuels. Failure of 321 stainless steel heater tube in heavy crude oil. Stress corrosion cracking of sensitized 304 austenitic. Results show that alloys 304 and 304l, in the solution. Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula s n so 3 h 2 n 2. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous.
This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Exposure to oxygen and water during turnaround forms polythionic acid and that leads to pta scc on sensitized stainless steel, where soda ash washing, nitrogen purge and pwht is required as a nace countermeasure. Weldability is better than tp347 and equal to that of tp304. Austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Overview of polythionic acid stress corrosion cracking pascc contribute to definition.
Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Standard recommended practice austenitic stainless steels. The polythionic acid stress corrosion cracking tests. It was further established that formation of polythionic acid due to presence of. Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. Resistant to chloride and polythionic acid stress corrosion cracking. The advantageous effect of nickel on limiting the stress corrosion cracking in boiling 42% mgcl2 is observed. Neutral chloride solutions also cause some cracking at room temperature, particularly if a thick. Chemical studies of polythionic acid stresscorrosion cracking.
Otherwise, through a scanning electron microscope sem fractograph, the extension of the crack on the. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. The effects of deformation, prior to sensitization, on intergranular stress corrosion cracking igscc were studied on the aisi 304 uns s30400 stainless steel ss.
Quizlet flashcards, activities and games help you improve your grades. Stress corrosion cracking can lead to catastrophic brittle failure. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. The paper presents an interesting finding, namely the occurrence of chloride stress corrosion cracking catalyzed by the presence of sulphurbearing species. Pdf polythionic acid corrosion in refinery hydroprocessors. Stress corrosion cracking susceptibility of stainless. It can also be utilized in chloride or fluoride free caustic solutions at moderate temperatures. Effects of sensitization and service fluid chemistry on polythionic acid stress corrosion cracking of 188 stainless steels authors eiki nagashima toyo engineering corp. The importance of a conjoint action of corrosion and stress as well as the nature of. Stress corrosion cracking of ring type joint of reactor. This standard is directed toward preventing stress corrosion cracking scc caused by polythionic acid pta that can be formed by reaction of oxygen and water with sulfide corrosion products i. Polythionic acid cracking is a type of intergranular corrosion affecting sensitized stainless steels in refineries processing sulfur containing feedstocks. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking scc can occur in a most metals and alloys due to the combined action of corrosion, tensile stress residual or applied and a susceptible microstructure.
Overview of polythionic acid stress corrosion cracking pascc. Polythionic acid sulfurous acids formed by the interaction of. Stress corrosion crac king scc is the growth of c rack formation in a corrosive environment. Stress corrosion cracking scc is the formation and growth of crack. Effect of chloride ion on stress corrosion cracking of type 316. These characteristics are consistent with stress corrosion cracking due to polythionic acids. The xrd test results show that the tensile residual stress occurred for the welding of the stainless steel clad plates. Polythionic stress corrosion cracking of stainless steel tube. Effects of sensitization and service fluid chemistry on. Heat treatment method for reducing polythionic acid stress. Corrosion behavior of inconel 625 heanjia super metals co. However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwaterchlorides along with metal sulfidesh2s to be reduced by adopting. Stress corrosion cracking scc may be defined as the delayed failure of alloys by. Standard practice for evaluating stresscorrosioncracking.
How is polythionic acid stress corrosion cracking oil refining abbreviated. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Any acid of the form h2sno6 having a chain of sulfur atoms. It was further established that formation of polythionic acid due to presence of h 2 s in the process gas and h 2 0 in the system was responsible for initiation of scc in rtj components. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. Stress corrosion cracking scc is one of the major contributors to the.
All of the cracks observed were found underneath the coke deposits. The cracking was found when rust stainingleaks were observed. Nov, 1990 in order to correlate the stress corrosion cracking response of alloy 617 in a polythionic acid pta environment with microstructure, selected samples in the asannealed and annealed plus heat treated conditions were examined in optical and scanning electron microscopes sem. Austenitic stainless steels are widely used in hydroprocessing units. Stresscorrosion cracking of sensitized type 304 stainless.
Sem image of fractured areas revealed the branch cracked through the. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. A welded joint has the excellent polythionic acid stress corrosion cracking resistance without pwht. Mechanical engineering assignment help, polythionic acid stress corrosion cracking, in naphtha hydrotreating unit, does feedeffluent heat exchangers require passivation to avoid polythionic acid stress corrosion cracking. A fire occurred at the fuel oil desulfurization cracking unit of a refinery 257 hours after startup of the plant, following a turnaround shutdown. Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist. Pascc stands for polythionic acid stress corrosion cracking oil refining. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Effect of surface treatment on the stress corrosion cracking.
Stress corrosion cracking of carbon steels has been identified as one of the main reasons leading to leakage and rupture events of pipe lines and steam. Alloy for resistance to polythionic acid stress corrosion. Pascc is defined as polythionic acid stress corrosion cracking oil refining somewhat frequently. Stress corrosion cracking behavior of nickel base alloys. Ctlpolythionic stress corrosion cracking of stainless. Polythionic acid stress corrosion cracking of type 310 stainless steel. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and fractography, in.
Alloy for resistance to polythionic acid stress corrosion cracking for. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled. The most damaging species identified to date are fluoride ions i and various metastable sulfur compounds. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Two classic cases of stress corrosion cracking are seasonal cracking of brass in. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304. Stresscorrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. Stress corrosion cracking leads to a hydrogen leak and. Nickel and nickel base alloys are normally resistant to chloride stress corrosion cracking as compared to stainless steels.
Citeseerx document details isaac councill, lee giles, pradeep teregowda. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. In this report, the literature on stress corrosion cracking scc of the candidate container materials for. Failure analysis performed of steel tube caused by polythionic stress cracking corrosion. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions.
This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing. Simply dilute with a low chloride water source and one 275gallon tote of pta treat will produce 10,000. Stresscorrosion cracking, materials performance and. Prevents polythionic acid stress corrosion cracking.
The precipitation of salts and coke from the heavy crude led to sensitization of the internal surface layer and sulphidation of the crack walls. Corrosion behavior of inconel 625 heanjia super metals. Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. The formulation is a premade liquid concentrate ready for field use. Intergranular corrosion tests were conducted by the copper sulfatesulfuric acid test in accordance with astm a262 practice e for 72hcuso 4h2so 4, solution 2. Scc stress corrosion cracking study guide by ivd includes 9 questions covering vocabulary, terms and more. Soda ash washing can be a costly and time consuming endeavor for the refiner. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Thus, the appearance of the crack may suggest that cracking could have been due to stress corrosion caused by polythionic acid or chloride and not to the creep. Brown chemistrydepartment theamericanuniversity washington,d. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail.
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